For example, the decay of potassium-40 to argon-40 is used to date rocks older than 20,000 years, and the decay of uranium-238 to lead-206 is used for rocks older than 1 million years.
Radiocarbon dating measures radioactive isotopes in once-living organic material instead of rock, using the decay of carbon-14 to nitrogen-14.
These rates of decay are known, so if you can measure the proportion of parent and daughter isotopes in rocks now, you can calculate when the rocks were formed.
Because of their unique decay rates, different elements are used for dating different age ranges.
Because of the fairly fast decay rate of carbon-14, it can only be used on material up to about 60,000 years old.
Geologists use radiocarbon to date such materials as wood and pollen trapped in sediment, which indicates the date of the sediment itself.
These use radioactive minerals in rocks as geological clocks.
All radiometric dating methods measure isotopes in some way.